Schedule, syllabus and examination date

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Course content

The course gives a thorough introduction to organometallic chemistry with focus on the transistion metals. The course starts with fundamental molecular properties and gradually develops this into practical applied catalysis. Structure and bonding issues in organometallic compounds are discussed in view of the 18-electron rule. Relevant and modern methods for characterization of organometallic compounds are described. Different reactive ligand types are discussed, including σ-bonded ligands such as alkyl, aryl, og hydride, as well as π-bonded ligands such as carbonyl, alkene, diene, alkyne, cyclopentadienyl, and arene. The properties of important ancillary ligands such as phosphine and N-heterocyclic carbenes are given special attention. Organometallic reaction mechanisms are thoroughly discussed with emphasis on ligand substitution, oxidative addition, reductive elimination, insertion and elimination reactions, nucleophilic and electrophilic addition and abstraction at ligands, and the involvement of carbenes in metathesis and polymerization. The accumulated know-how at this point serves as the foundation for discussions about how organometallic complexes are utilized in homogeneous catalysis and in the activation of small molecules. The application of organometallics in catalysis is highlighted with selected important industrial processes.

Learning outcome

Having complete the course you should:

• have a good overview of the fundamental principles of organotransition-metal chemistry and know how chemical properties are affected by metals and ligands.

• be able to use knowledge about structure and bonding issues to understand the stability and reactivity of simple organometallic complexes.

• have insight into the use of modern methods to characterize organometallic compounds.

• understand fundamental reaction types and mechanisms and how to combine these to understand efficient catalytic processes

• know important applications of organometallic homogeneous catalysis in the production of large-scale (bulk) and smaller-scale (fine chemicals) production.

Admission

Students who are admitted to study programmes at UiO must each semester register which courses and exams they wish to sign up for in Studentweb.

If you are not already enrolled as a student at UiO, please see our information about admission requirements and procedures.

Prerequisites

Recommended previous knowledge

One or more of KJM3000 - Applied spectroscopy, KJM4200 - Organic Chemistry II (discontinued), KJM3300 - Physical Chemistry II (discontinued) will form a good starting point.

Overlapping courses

10 credits overlap with KJM9210 - Organometallic Chemistry

Teaching

The course comprises 36-40 hours of lectures and 8 hours of group seminars.

The first lecture is mandatory. If you are unable to attend, the Expedition Office has to be informed in advance (phone 22 85 54 46, or e-mail ekspedisjonen@kjemi.uio.no), or else you will lose your place in the course.

Examination

Oral exam.

Grading scale

Grades are awarded on a scale from A to F, where A is the best grade and F is a fail. Read more about the grading system.

Explanations and appeals

Resit an examination

Students who can document a valid reason for absence from the regular examination are offered a postponed examination at the beginning of the next semester.

Re-scheduled examinations are not offered to students who withdraw during, or did not pass the original examination.

Facts about this course

Credits

10

Level

Master

Teaching

Autumn 2016

Autumn 2014

Every fourth semester from autumn 2010. Teaching may be cancelled if less than 5 students apply.

Examination

Autumn 2014

Autumn 2012

Every fourth semester.

Teaching language

Norwegian (English on request)